Thermochemical and trace element behavior of coal gangue, agricultural biomass and their blends during co-combustion

Chuncai Zhou, Guijian Liu, Siwei Cheng, Ting Fang, Paul Kwan Sing Lam

Research output: Contribution to journalArticlepeer-review

92 Citations (Scopus)

Abstract

The thermal decomposition behavior of coal gangue, peanut shell, wheat straw and their blends during combustion were determined via thermogravimetric analysis. The coal gangue/agricultural biomass blends were prepared in four weight ratios and oxidized under dynamic conditions from room temperature to 1000. °C by various heating rates. Kinetic models were carried out to evaluate the thermal reactivity. The overall mass balance was performed to assess the partition behavior of coal gangue, peanut shell and their blends during combustion in a fixed bed reactor. The decomposition processes of agricultural biomass included evaporation, release of volatile matter and combustion as well as char oxidation. The thermal reactivity of coal gangue could be improved through the addition of agricultural biomass in suitable proportion and subsequent appropriate heating rate during combustion. In combination with the heating value and base/acid ratio limitations, a blending ratio of 30% agricultural biomass is conservatively selected as optimum blending.

Original languageEnglish
Pages (from-to)243-251
Number of pages9
JournalBioresource Technology
Volume166
DOIs
Publication statusPublished - Aug 2014
Externally publishedYes

Keywords

  • Agricultural biomass
  • Co-combustion
  • Coal gangue
  • Reactivity
  • Trace element

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