Syntheses, crystal structures and photocatalytic properties of transition metal complexes based on 9,10-anthraquinone-1,3-dicarboxylate

Cai Ping Ye; Rong Ling; Lin Feng Yang; Qi Zhang; Jie Han; Xu Dong Chen

doi:10.1007/s11243-019-00334-2

Syntheses, crystal structures and photocatalytic properties of transition metal complexes based on 9,10-anthraquinone-1,3-dicarboxylate

Cai Ping Ye
, Rong Ling
, Lin Feng Yang
, Qi Zhang
, Jie Han
, Xu Dong Chen

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Five transition metal complexes based on the ligand 9,10-anthraquinone-1,3-dicarboxylate acid (1,3-H₂AQDC) have been synthesized and characterized by physico-chemical and spectroscopic methods. Single-crystal analyses show that the complexes {Mn(1,3-AQDC)(H₂O)₄·(H₂O)}_n, {Zn(1,3-AQDC)(H₂O)₄·(H₂O)}_n, {Ni(1,3-AQDC)(4,4′-bpy)(H₂O)₂(CH₃OH)}_n and {Co(1,3-AQDC)(4,4′-bpy)(H₂O)₂(CH₃OH)}_n (4,4′-bpy = 4,4′-bipyridine) comprise one-dimensional (1D) chains in their crystal structures, while [Ni(1,3-AQDC)(H₂O)₄·(H₂O)₃]₂ bears dimeric units, and these secondary building units are further linked by hydrogen bonding to form three-dimensional structures. These compounds proved to be able to catalyze visible-light-driven air-oxidation reactions of diarylethyne into diketones under mild conditions.

Original language	English
Pages (from-to)	475-482
Number of pages	8
Journal	Transition Metal Chemistry
Volume	44
Issue number	5
DOIs	https://doi.org/10.1007/s11243-019-00334-2
Publication status	Published - 15 Aug 2019

Access to Document

10.1007/s11243-019-00334-2

Cite this

@article{e05f74e4f33e4e12b28bbd76a27640f6,

title = "Syntheses, crystal structures and photocatalytic properties of transition metal complexes based on 9,10-anthraquinone-1,3-dicarboxylate",

abstract = "Five transition metal complexes based on the ligand 9,10-anthraquinone-1,3-dicarboxylate acid (1,3-H2AQDC) have been synthesized and characterized by physico-chemical and spectroscopic methods. Single-crystal analyses show that the complexes \{Mn(1,3-AQDC)(H2O)4·(H2O)\}n, \{Zn(1,3-AQDC)(H2O)4·(H2O)\}n, \{Ni(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)\}n and \{Co(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)\}n (4,4′-bpy = 4,4′-bipyridine) comprise one-dimensional (1D) chains in their crystal structures, while [Ni(1,3-AQDC)(H2O)4·(H2O)3]2 bears dimeric units, and these secondary building units are further linked by hydrogen bonding to form three-dimensional structures. These compounds proved to be able to catalyze visible-light-driven air-oxidation reactions of diarylethyne into diketones under mild conditions.",

author = "Ye, \{Cai Ping\} and Rong Ling and Yang, \{Lin Feng\} and Qi Zhang and Jie Han and Chen, \{Xu Dong\}",

note = "Publisher Copyright: {\textcopyright} 2019, Springer Nature Switzerland AG.",

year = "2019",

month = aug,

day = "15",

doi = "10.1007/s11243-019-00334-2",

language = "English",

volume = "44",

pages = "475--482",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Science and Business Media Deutschland GmbH",

number = "5",

}

TY - JOUR

T1 - Syntheses, crystal structures and photocatalytic properties of transition metal complexes based on 9,10-anthraquinone-1,3-dicarboxylate

AU - Ye, Cai Ping

AU - Ling, Rong

AU - Yang, Lin Feng

AU - Zhang, Qi

AU - Han, Jie

AU - Chen, Xu Dong

PY - 2019/8/15

Y1 - 2019/8/15

N2 - Five transition metal complexes based on the ligand 9,10-anthraquinone-1,3-dicarboxylate acid (1,3-H2AQDC) have been synthesized and characterized by physico-chemical and spectroscopic methods. Single-crystal analyses show that the complexes {Mn(1,3-AQDC)(H2O)4·(H2O)}n, {Zn(1,3-AQDC)(H2O)4·(H2O)}n, {Ni(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)}n and {Co(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)}n (4,4′-bpy = 4,4′-bipyridine) comprise one-dimensional (1D) chains in their crystal structures, while [Ni(1,3-AQDC)(H2O)4·(H2O)3]2 bears dimeric units, and these secondary building units are further linked by hydrogen bonding to form three-dimensional structures. These compounds proved to be able to catalyze visible-light-driven air-oxidation reactions of diarylethyne into diketones under mild conditions.

AB - Five transition metal complexes based on the ligand 9,10-anthraquinone-1,3-dicarboxylate acid (1,3-H2AQDC) have been synthesized and characterized by physico-chemical and spectroscopic methods. Single-crystal analyses show that the complexes {Mn(1,3-AQDC)(H2O)4·(H2O)}n, {Zn(1,3-AQDC)(H2O)4·(H2O)}n, {Ni(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)}n and {Co(1,3-AQDC)(4,4′-bpy)(H2O)2(CH3OH)}n (4,4′-bpy = 4,4′-bipyridine) comprise one-dimensional (1D) chains in their crystal structures, while [Ni(1,3-AQDC)(H2O)4·(H2O)3]2 bears dimeric units, and these secondary building units are further linked by hydrogen bonding to form three-dimensional structures. These compounds proved to be able to catalyze visible-light-driven air-oxidation reactions of diarylethyne into diketones under mild conditions.

UR - https://www.scopus.com/pages/publications/85066994196

U2 - 10.1007/s11243-019-00334-2

DO - 10.1007/s11243-019-00334-2

M3 - Article

AN - SCOPUS:85066994196

SN - 0340-4285

VL - 44

SP - 475

EP - 482

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 5

ER -

Syntheses, crystal structures and photocatalytic properties of transition metal complexes based on 9,10-anthraquinone-1,3-dicarboxylate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this