Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment

Lutz Ahrens; Leo W.Y. Yeung; Sachi Taniyasu; Paul K.S. Lam; Nobuyoshi Yamashita

doi:10.1016/j.chemosphere.2011.06.046

Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment

Lutz Ahrens
, Leo W.Y. Yeung
, Sachi Taniyasu
, Paul K.S. Lam
, Nobuyoshi Yamashita

Research output: Contribution to journal › Article › peer-review

230 Citations (Scopus)

Abstract

Laboratory partitioning experiments were conducted to elucidate the sorption behaviour and partitioning of perfluoroalkyl compounds (PFCs). Three different sediment types were used and separately spiked with perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) at low environmentally realistic concentrations. PFOA, PFOS and PFOSA were mainly distributed in the dissolved phase at low suspended solid concentrations, indicating their long-range transport potential in the marine environment. In all cases, the equilibrium isotherms were linear and the organic carbon normalised partition coefficients (K_OC) decreased in the following order: PFOSA (log K_OC=4.1±0.35cm³g^-1)>PFOS (3.7±0.56cm³g^-1)>PFOA (2.4±0.12cm³g^-1). The level of organic content had a significant influence on the partitioning. For the sediment with negligible organic content the density of the sediment became the most important factor influencing the partitioning. Ultimately, data on the partitioning of PFCs between aqueous media and suspended solids are essential for modelling their transport and environmental fate.

Original language	English
Pages (from-to)	731-737
Number of pages	7
Journal	Chemosphere
Volume	85
Issue number	5
DOIs	https://doi.org/10.1016/j.chemosphere.2011.06.046
Publication status	Published - Oct 2011
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 3 Good Health and Well-being
SDG 14 Life Below Water

Keywords

PFCs
PFOA
PFOS
PFOSA
Partitioning
Sediment

Access to Document

10.1016/j.chemosphere.2011.06.046

Cite this

@article{bc6b83c670744a748c02bf5175b3f1eb,

title = "Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment",

abstract = "Laboratory partitioning experiments were conducted to elucidate the sorption behaviour and partitioning of perfluoroalkyl compounds (PFCs). Three different sediment types were used and separately spiked with perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) at low environmentally realistic concentrations. PFOA, PFOS and PFOSA were mainly distributed in the dissolved phase at low suspended solid concentrations, indicating their long-range transport potential in the marine environment. In all cases, the equilibrium isotherms were linear and the organic carbon normalised partition coefficients (KOC) decreased in the following order: PFOSA (log KOC=4.1±0.35cm3g-1)>PFOS (3.7±0.56cm3g-1)>PFOA (2.4±0.12cm3g-1). The level of organic content had a significant influence on the partitioning. For the sediment with negligible organic content the density of the sediment became the most important factor influencing the partitioning. Ultimately, data on the partitioning of PFCs between aqueous media and suspended solids are essential for modelling their transport and environmental fate.",

keywords = "PFCs, PFOA, PFOS, PFOSA, Partitioning, Sediment",

author = "Lutz Ahrens and Yeung, \{Leo W.Y.\} and Sachi Taniyasu and Lam, \{Paul K.S.\} and Nobuyoshi Yamashita",

note = "Funding Information: The authors acknowledged the German Federal Environmental Foundation and International Bureau from the Federal Ministry of Education and Research (project JPN 08/A02) for supporting the project. P.K.S.L. and L.W.Y.Y. were supported by the Area of Excellence Scheme under the University Grants Committee of the Hong Kong Special Administrative Region, China (Project No. AoE/P-04/2004). ",

year = "2011",

month = oct,

doi = "10.1016/j.chemosphere.2011.06.046",

language = "English",

volume = "85",

pages = "731--737",

number = "5",

}

TY - JOUR

T1 - Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment

AU - Ahrens, Lutz

AU - Yeung, Leo W.Y.

AU - Taniyasu, Sachi

AU - Lam, Paul K.S.

AU - Yamashita, Nobuyoshi

N1 - Funding Information: The authors acknowledged the German Federal Environmental Foundation and International Bureau from the Federal Ministry of Education and Research (project JPN 08/A02) for supporting the project. P.K.S.L. and L.W.Y.Y. were supported by the Area of Excellence Scheme under the University Grants Committee of the Hong Kong Special Administrative Region, China (Project No. AoE/P-04/2004).

PY - 2011/10

Y1 - 2011/10

N2 - Laboratory partitioning experiments were conducted to elucidate the sorption behaviour and partitioning of perfluoroalkyl compounds (PFCs). Three different sediment types were used and separately spiked with perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) at low environmentally realistic concentrations. PFOA, PFOS and PFOSA were mainly distributed in the dissolved phase at low suspended solid concentrations, indicating their long-range transport potential in the marine environment. In all cases, the equilibrium isotherms were linear and the organic carbon normalised partition coefficients (KOC) decreased in the following order: PFOSA (log KOC=4.1±0.35cm3g-1)>PFOS (3.7±0.56cm3g-1)>PFOA (2.4±0.12cm3g-1). The level of organic content had a significant influence on the partitioning. For the sediment with negligible organic content the density of the sediment became the most important factor influencing the partitioning. Ultimately, data on the partitioning of PFCs between aqueous media and suspended solids are essential for modelling their transport and environmental fate.

AB - Laboratory partitioning experiments were conducted to elucidate the sorption behaviour and partitioning of perfluoroalkyl compounds (PFCs). Three different sediment types were used and separately spiked with perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) at low environmentally realistic concentrations. PFOA, PFOS and PFOSA were mainly distributed in the dissolved phase at low suspended solid concentrations, indicating their long-range transport potential in the marine environment. In all cases, the equilibrium isotherms were linear and the organic carbon normalised partition coefficients (KOC) decreased in the following order: PFOSA (log KOC=4.1±0.35cm3g-1)>PFOS (3.7±0.56cm3g-1)>PFOA (2.4±0.12cm3g-1). The level of organic content had a significant influence on the partitioning. For the sediment with negligible organic content the density of the sediment became the most important factor influencing the partitioning. Ultimately, data on the partitioning of PFCs between aqueous media and suspended solids are essential for modelling their transport and environmental fate.

KW - PFCs

KW - PFOA

KW - PFOS

KW - PFOSA

KW - Partitioning

KW - Sediment

UR - https://www.scopus.com/pages/publications/80555126789

U2 - 10.1016/j.chemosphere.2011.06.046

DO - 10.1016/j.chemosphere.2011.06.046

M3 - Article

C2 - 21742366

AN - SCOPUS:80555126789

SN - 0045-6535

VL - 85

SP - 731

EP - 737

JO - Chemosphere

JF - Chemosphere

IS - 5

ER -

Partitioning of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS) and perfluorooctane sulfonamide (PFOSA) between water and sediment

Abstract

UN SDGs

Keywords

Access to Document

Other files and links

Fingerprint

Cite this