Nondirected C-H Bond Functionalizations of (Hetero)arenes

Shun Man Wong; Fuk Yee Kwong

doi:10.1016/B978-0-12-805254-9.00003-7

Nondirected C-H Bond Functionalizations of (Hetero)arenes

Shun Man Wong
, Fuk Yee Kwong

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

7 Citations (Scopus)

Abstract

Catalytic C-H functionalization falls into three categories: (1) the reaction of a (hetero)arene C-H bond with a (pseudo)halide; (2) the reaction of a (hetero)arene C-H bond with an organometallic reagent; and (3) the reaction between two (hetero)arene C-H bonds. The first type of reaction is oxidation-neutral, while the second and third types of reaction require a sacrificial oxidant. Herein, selected representative examples for intermolecular nondirected C-H bond functionalizations of (hetero)arenes with (pseudo)halides for constructing bi(hetero)aryl derivatives, in recent decades, are described.

Original language	English
Title of host publication	Strategies for Palladium-Catalyzed Non-directed and Directed C bond H Bond Functionalization
Pages	49-166
Number of pages	118
ISBN (Electronic)	9780128052556
DOIs	https://doi.org/10.1016/B978-0-12-805254-9.00003-7
Publication status	Published - 25 May 2017
Externally published	Yes

Keywords

(hetero)arenes
(pseudo)halides
C-H functionalization
Catalysis
Nondirected
Palladium

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10.1016/B978-0-12-805254-9.00003-7

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abstract = "Catalytic C-H functionalization falls into three categories: (1) the reaction of a (hetero)arene C-H bond with a (pseudo)halide; (2) the reaction of a (hetero)arene C-H bond with an organometallic reagent; and (3) the reaction between two (hetero)arene C-H bonds. The first type of reaction is oxidation-neutral, while the second and third types of reaction require a sacrificial oxidant. Herein, selected representative examples for intermolecular nondirected C-H bond functionalizations of (hetero)arenes with (pseudo)halides for constructing bi(hetero)aryl derivatives, in recent decades, are described.",

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T1 - Nondirected C-H Bond Functionalizations of (Hetero)arenes

AU - Wong, Shun Man

AU - Kwong, Fuk Yee

PY - 2017/5/25

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N2 - Catalytic C-H functionalization falls into three categories: (1) the reaction of a (hetero)arene C-H bond with a (pseudo)halide; (2) the reaction of a (hetero)arene C-H bond with an organometallic reagent; and (3) the reaction between two (hetero)arene C-H bonds. The first type of reaction is oxidation-neutral, while the second and third types of reaction require a sacrificial oxidant. Herein, selected representative examples for intermolecular nondirected C-H bond functionalizations of (hetero)arenes with (pseudo)halides for constructing bi(hetero)aryl derivatives, in recent decades, are described.

AB - Catalytic C-H functionalization falls into three categories: (1) the reaction of a (hetero)arene C-H bond with a (pseudo)halide; (2) the reaction of a (hetero)arene C-H bond with an organometallic reagent; and (3) the reaction between two (hetero)arene C-H bonds. The first type of reaction is oxidation-neutral, while the second and third types of reaction require a sacrificial oxidant. Herein, selected representative examples for intermolecular nondirected C-H bond functionalizations of (hetero)arenes with (pseudo)halides for constructing bi(hetero)aryl derivatives, in recent decades, are described.

KW - (hetero)arenes

KW - (pseudo)halides

KW - C-H functionalization

KW - Catalysis

KW - Nondirected

KW - Palladium

UR - https://www.scopus.com/pages/publications/85054240580

U2 - 10.1016/B978-0-12-805254-9.00003-7

DO - 10.1016/B978-0-12-805254-9.00003-7

M3 - Chapter

AN - SCOPUS:85054240580

SN - 9780128052549

SP - 49

EP - 166

BT - Strategies for Palladium-Catalyzed Non-directed and Directed C bond H Bond Functionalization

ER -

Nondirected C-H Bond Functionalizations of (Hetero)arenes

Abstract

Keywords

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