Abstract
The size of electrodes in bio-chemical sensors has shrunk quickly in recent years. The high impedance from polarizable microelectrodes brings new challenges to the sensor design. On the other hand, non-polarizable electrodes, such as Ag/AgCl electrodes, could have lower impedance at the low bio-signal frequency band. Thin-film Ag/AgCl electrode is commonly used as reference electrode. In this work, the electrochemical processes governing the impedance profile of thin film Ag/AgCl microelectrodes are systematically studied. New models are established for circuit parameters of thin film Ag/AgCl microelectrodes based on the new findings. The models are verified extensively with impedance measurements.
| Original language | English |
|---|---|
| Article number | 134638 |
| Journal | Electrochimica Acta |
| Volume | 320 |
| DOIs | |
| Publication status | Published - 10 Oct 2019 |
| Externally published | Yes |
Keywords
- Ag/AgCl electrode
- Impedance modeling
- Non-polarizable electrode
- Randles equivalent circuit
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