A neutral Cu-based MOF for effective quercetin extraction and conversion from natural onion juice

Rui Qi Xiang; Yan Fei Niu; Jie Han; Yat Long Lau; Hai Hong Wu; Xiao Li Zhao

doi:10.1039/c9ra04551a

A neutral Cu-based MOF for effective quercetin extraction and conversion from natural onion juice

Rui Qi Xiang
, Yan Fei Niu
, Jie Han
, Yat Long Lau
, Hai Hong Wu
, Xiao Li Zhao

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

We report herein a new microporous neutral three-dimensional (3D) metal-organic framework [Cu₂(L)(DMF)(H₂O)]·guest (1·guest) composed of copper paddle-wheel and flexible tetracarboxylic acid linkers (DMF = N,N-dimethylformamide, H₄L = tetrakis[(6-carboxynaphthoxy)methyl]methane). Surprisingly, this MOF with neutral cavities can not only extract pure quercetin (QT) but also convert it into Cu-QT during the desorption process. It has been well characterized by UV-vis, IR, ESI-MS and TEM-EDS studies. Moreover, it can efficiently extract natural product QT from fresh QT-rich onion juice and rapidly convert it into Cu-QT with a relatively high conversion rate.

Original language	English
Pages (from-to)	33716-33721
Number of pages	6
Journal	RSC Advances
Volume	9
Issue number	58
DOIs	https://doi.org/10.1039/c9ra04551a
Publication status	Published - 2019

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title = "A neutral Cu-based MOF for effective quercetin extraction and conversion from natural onion juice",

abstract = "We report herein a new microporous neutral three-dimensional (3D) metal-organic framework [Cu2(L)(DMF)(H2O)]·guest (1·guest) composed of copper paddle-wheel and flexible tetracarboxylic acid linkers (DMF = N,N-dimethylformamide, H4L = tetrakis[(6-carboxynaphthoxy)methyl]methane). Surprisingly, this MOF with neutral cavities can not only extract pure quercetin (QT) but also convert it into Cu-QT during the desorption process. It has been well characterized by UV-vis, IR, ESI-MS and TEM-EDS studies. Moreover, it can efficiently extract natural product QT from fresh QT-rich onion juice and rapidly convert it into Cu-QT with a relatively high conversion rate.",

author = "Xiang, \{Rui Qi\} and Niu, \{Yan Fei\} and Jie Han and Lau, \{Yat Long\} and Wu, \{Hai Hong\} and Zhao, \{Xiao Li\}",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9ra04551a",

language = "English",

volume = "9",

pages = "33716--33721",

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TY - JOUR

T1 - A neutral Cu-based MOF for effective quercetin extraction and conversion from natural onion juice

AU - Xiang, Rui Qi

AU - Niu, Yan Fei

AU - Han, Jie

AU - Lau, Yat Long

AU - Wu, Hai Hong

AU - Zhao, Xiao Li

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - We report herein a new microporous neutral three-dimensional (3D) metal-organic framework [Cu2(L)(DMF)(H2O)]·guest (1·guest) composed of copper paddle-wheel and flexible tetracarboxylic acid linkers (DMF = N,N-dimethylformamide, H4L = tetrakis[(6-carboxynaphthoxy)methyl]methane). Surprisingly, this MOF with neutral cavities can not only extract pure quercetin (QT) but also convert it into Cu-QT during the desorption process. It has been well characterized by UV-vis, IR, ESI-MS and TEM-EDS studies. Moreover, it can efficiently extract natural product QT from fresh QT-rich onion juice and rapidly convert it into Cu-QT with a relatively high conversion rate.

AB - We report herein a new microporous neutral three-dimensional (3D) metal-organic framework [Cu2(L)(DMF)(H2O)]·guest (1·guest) composed of copper paddle-wheel and flexible tetracarboxylic acid linkers (DMF = N,N-dimethylformamide, H4L = tetrakis[(6-carboxynaphthoxy)methyl]methane). Surprisingly, this MOF with neutral cavities can not only extract pure quercetin (QT) but also convert it into Cu-QT during the desorption process. It has been well characterized by UV-vis, IR, ESI-MS and TEM-EDS studies. Moreover, it can efficiently extract natural product QT from fresh QT-rich onion juice and rapidly convert it into Cu-QT with a relatively high conversion rate.

UR - https://www.scopus.com/pages/publications/85074543636

U2 - 10.1039/c9ra04551a

DO - 10.1039/c9ra04551a

M3 - Article

AN - SCOPUS:85074543636

VL - 9

SP - 33716

EP - 33721

JO - RSC Advances

JF - RSC Advances

IS - 58

ER -

A neutral Cu-based MOF for effective quercetin extraction and conversion from natural onion juice

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